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Synthesis of γ,δ-Unsaturated Glycolic Acids via Sequenced Brook and Ireland-Claisen Rearrangements

[Image: see text] Organozinc, magnesium, and lithium nucleophiles initiate a Brook/Ireland-Claisen rearrangement sequence of allylic silyl glyoxylates resulting in formation of γ,δ-unsaturated α-silyloxy acids.

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書目詳細資料
Main Authors: Schmitt, Daniel C., Johnson, Jeffrey S.
格式: Artigo
語言:Inglês
出版: 2010
主題:
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2830285/
https://ncbi.nlm.nih.gov/pubmed/20143793
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol9029353
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