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Engaging Alkenes and Alkynes in Deaminative Alkyl–Alkyl and Alkyl–Vinyl Cross-Couplings of Alkylpyridinium Salts

An alkyl–alkyl cross-coupling of alkylpyridinium salts and organoboranes, formed in situ via hydroboration of alkenes, has been developed. This method utilizes the abundance of both alkyl amine precursors and alkenes to form C(sp(3))─C(sp(3)) bonds. This strategy is also effective with alkynes, enab...

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Bibliographische Detailangaben
Veröffentlicht in:Org Lett
Hauptverfasser: Baker, Kristen M., Baca, Diana Lucas, Plunkett, Shane, Daneker, Mitchell E., Watson, Mary P.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2019
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6933946/
https://ncbi.nlm.nih.gov/pubmed/31763855
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b03899
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