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Engaging Alkenes and Alkynes in Deaminative Alkyl–Alkyl and Alkyl–Vinyl Cross-Couplings of Alkylpyridinium Salts

An alkyl–alkyl cross-coupling of alkylpyridinium salts and organoboranes, formed in situ via hydroboration of alkenes, has been developed. This method utilizes the abundance of both alkyl amine precursors and alkenes to form C(sp(3))─C(sp(3)) bonds. This strategy is also effective with alkynes, enab...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Baker, Kristen M., Baca, Diana Lucas, Plunkett, Shane, Daneker, Mitchell E., Watson, Mary P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6933946/
https://ncbi.nlm.nih.gov/pubmed/31763855
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b03899
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