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Heme–Cu Binucleating Ligand Supports Heme/O(2) and Fe(II)−Cu(I)/O(2) Reactivity Providing High- and Low-Spin Fe(III)−Peroxo−Cu(II) Complexes
The focus of this study is in the description of synthetic heme/copper/O(2) chemistry employing a hemecontaining binucleating ligand which provides a tridentate chelate for copper ion binding. The addition of O(2) (−80 °C, tetrahydrofuran (THF) solvent) to the reduced heme compound (P(ImH))Fe(II) (1...
Αποθηκεύτηκε σε:
| Τόπος έκδοσης: | Inorg Chem |
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| Κύριοι συγγραφείς: | , , , , |
| Μορφή: | Artigo |
| Γλώσσα: | Inglês |
| Έκδοση: |
2019
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| Θέματα: | |
| Διαθέσιμο Online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6916717/ https://ncbi.nlm.nih.gov/pubmed/31657921 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b02521 |
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