Superoxo, μ-peroxo, and μ-oxo complexes from heme/O(2) and heme-Cu/O(2) reactivity: Copper ligand influences in cytochrome c oxidase models

The O(2)-reaction chemistry of 1:1 mixtures of (F(8))Fe(II) (1; F(8) = tetrakis(2,6-diflurorophenyl)porphyrinate) and [(L(Me(2))(N))Cu(I)](+) (2; L(Me(2))(N) = N,N-bis{2-[2-(N′,N′-4-dimethylamino)pyridyl]ethyl}methylamine) is described, to model aspects of the chemistry occurring in cytochrome c oxi...

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Detalhes bibliográficos
Main Authors: Kim, Eunsuk, Helton, Matthew E., Wasser, Ian M., Karlin, Kenneth D., Lu, Shen, Huang, Hong-wei, Moënne-Loccoz, Pierre, Incarvito, Christopher D., Rheingold, Arnold L., Honecker, Marcus, Kaderli, Susan, Zuberbühler, Andreas D.
Formato: Artigo
Idioma:Inglês
Publicado em: The National Academy of Sciences 2003
Assuntos:
Physical Sciences
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC152972/
https://ncbi.nlm.nih.gov/pubmed/12655050
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0737180100
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