Superoxo, μ-peroxo, and μ-oxo complexes from heme/O(2) and heme-Cu/O(2) reactivity: Copper ligand influences in cytochrome c oxidase models

The O(2)-reaction chemistry of 1:1 mixtures of (F(8))Fe(II) (1; F(8) = tetrakis(2,6-diflurorophenyl)porphyrinate) and [(L(Me(2))(N))Cu(I)](+) (2; L(Me(2))(N) = N,N-bis{2-[2-(N′,N′-4-dimethylamino)pyridyl]ethyl}methylamine) is described, to model aspects of the chemistry occurring in cytochrome c oxi...

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Pubblicato in:	Proc Natl Acad Sci U S A
Autori principali:	Kim, Eunsuk, Helton, Matthew E., Wasser, Ian M., Karlin, Kenneth D., Lu, Shen, Huang, Hong-wei, Moënne-Loccoz, Pierre, Incarvito, Christopher D., Rheingold, Arnold L., Honecker, Marcus, Kaderli, Susan, Zuberbühler, Andreas D.
Natura:	Artigo
Lingua:	Inglês
Pubblicazione:	National Academy of Sciences 2003
Soggetti:	Physical Sciences
Accesso online:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC152972/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/12655050/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.0737180100
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