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Cooperative H(2) Activation on Dicopper(I) Facilitated by Reversible Dearomatization of an “Expanded PNNP Pincer” Ligand
A naphthyridine‐derived expanded pincer ligand is described that can host two copper(I) centers. The proton‐responsive ligand can undergo reversible partial and full dearomatization of the naphthyridine core, which enables cooperative activation of H(2) giving an unusual butterfly‐shaped Cu(4)H(2) c...
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| Опубликовано в: : | Chemistry |
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| Главные авторы: | , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
John Wiley and Sons Inc.
2019
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6856846/ https://ncbi.nlm.nih.gov/pubmed/31424132 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201903724 |
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