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Hydration of nitriles using a metal–ligand cooperative ruthenium pincer catalyst

Nitrile hydration provides access to amides that are important structural elements in organic chemistry. Here we report catalytic nitrile hydration using ruthenium catalysts based on a pincer scaffold with a dearomatized pyridine backbone. These complexes catalyze the nucleophilic addition of H(2)O...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Guo, Beibei, de Vries, Johannes G., Otten, Edwin
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2019
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7020783/
https://ncbi.nlm.nih.gov/pubmed/32110350
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc04624k
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