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Oxa‐Michael Addition to α,β‐Unsaturated Nitriles: An Expedient Route to γ‐Amino Alcohols and Derivatives

Water addition to α,β‐unsaturated nitriles would give facile access to the β‐hydroxy‐nitriles, which in turn can be hydrogenated to the γ‐amino alcohols. We have previously shown that alcohols readily add in 1,4‐fashion to these substrates using Milstein's Ru(PNN) pincer complex as catalyst. Ho...

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Publicat a:ChemCatChem
Autors principals: Guo, Beibei, Zijlstra, Douwe S., de Vries, Johannes G., Otten, Edwin
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2018
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6147005/
https://ncbi.nlm.nih.gov/pubmed/30263082
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cctc.201800509
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