Cyclometalated Ruthenium Pincer Complexes as Catalysts for the α‐Alkylation of Ketones with Alcohols

Ruthenium PNP pincer complexes bearing supplementary cyclometalated C,N‐bound ligands have been prepared and fully characterized for the first time. By replacing CO and H(−) as ancillary ligands in such complexes, additional electronic and steric modifications of this topical class of catalysts are...

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Publicado en:Chemistry
Autores principales: Piehl, Patrick, Amuso, Roberta, Alberico, Elisabetta, Junge, Henrik, Gabriele, Bartolo, Neumann, Helfried, Beller, Matthias
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2020
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317879/
https://ncbi.nlm.nih.gov/pubmed/31985105
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000396
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