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Cyclometalated Ruthenium Pincer Complexes as Catalysts for the α‐Alkylation of Ketones with Alcohols

Ruthenium PNP pincer complexes bearing supplementary cyclometalated C,N‐bound ligands have been prepared and fully characterized for the first time. By replacing CO and H(−) as ancillary ligands in such complexes, additional electronic and steric modifications of this topical class of catalysts are...

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Publicado en:Chemistry
Main Authors: Piehl, Patrick, Amuso, Roberta, Alberico, Elisabetta, Junge, Henrik, Gabriele, Bartolo, Neumann, Helfried, Beller, Matthias
Formato: Artigo
Idioma:Inglês
Publicado: John Wiley and Sons Inc. 2020
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317879/
https://ncbi.nlm.nih.gov/pubmed/31985105
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000396
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