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Towards a general ruthenium-catalyzed hydrogenation of secondary and tertiary amides to amines
A broad range of secondary and tertiary amides has been hydrogenated to the corresponding amines under mild conditions using an in situ catalyst generated by combining [Ru(acac)(3)], 1,1,1-tris(diphenylphosphinomethyl)ethane (Triphos) and Yb(OTf)(3). The presence of the metal triflate allows to miti...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6006866/ https://ncbi.nlm.nih.gov/pubmed/29997838 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04671h |
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