Metal–Ligand Cooperation Facilitates Bond Activation and Catalytic Hydrogenation with Zinc Pincer Complexes

[Image: see text] A series of PNP zinc pincer complexes capable of bond activation via aromatization/dearomatization metal–ligand cooperation (MLC) were prepared and characterized. Reversible heterolytic N–H and H–H bond activation by MLC is shown, in which hemilability of the phosphorus linkers pla...

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Vydáno v:J Am Chem Soc
Hlavní autoři: Rauch, Michael, Kar, Sayan, Kumar, Amit, Avram, Liat, Shimon, Linda J. W., Milstein, David
Médium: Artigo
Jazyk:Inglês
Vydáno: American Chemical Society 2020
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7453403/
https://ncbi.nlm.nih.gov/pubmed/32786799
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c05500
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