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Metal–Ligand Cooperation as Key in Formation of Dearomatized Ni(II)–H Pincer Complexes and in Their Reactivity toward CO and CO(2)
[Image: see text] The unique synthesis and reactivity of [((R)PNP*)NiH] complexes (1a,b), based on metal–ligand cooperation (MLC), are presented ((R)PNP* = deprotonated PNP ligand, R = (i)Pr, (t)Bu). Unexpectedly, the dearomatized complexes 1a,b were obtained by reduction of the dicationic complexes...
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| Опубликовано в: : | Organometallics |
|---|---|
| Главные авторы: | , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
American Chemical
Society
2018
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| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6503609/ https://ncbi.nlm.nih.gov/pubmed/31080304 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.8b00160 |
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