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Structure of a Ferryl Mimic in the Archetypal Iron(II)- and 2-(Oxo)-glutarate-Dependent Dioxygenase, TauD

Iron(II)- and 2-(oxo)-glutarate-dependent (Fe/2OG) oxygenases catalyze a diverse array of oxidation reactions via a common iron(IV)-oxo (ferryl) intermediate. Although the intermediate has been characterized spectroscopically, its short lifetime has precluded crystallograhic characterization. In sol...

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Detalhes bibliográficos
Publicado no:Biochemistry
Main Authors: Davis, Katherine M., Altmyer, Madison, Martinie, Ryan J., Schaperdoth, Irene, Krebs, Carsten, Bollinger, J. Martin, Boal, Amie K.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6800575/
https://ncbi.nlm.nih.gov/pubmed/31503454
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.9b00598
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