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Vanadyl as a Stable Structural Mimic of Reactive Ferryl Intermediates in Mononuclear Non-heme-iron Enzymes

The iron(II)- and 2-(oxo)glutarate-dependent (Fe/2OG) oxygenases catalyze an array of challenging transformations via a common iron(IV)-oxo (ferryl) intermediate, which in most cases abstracts hydrogen (H•) from an aliphatic carbon of the substrate. Although it has been shown that the relative dispo...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Martinie, Ryan J., Pollock, Christopher J., Matthews, Megan L., Bollinger, J. Martin, Krebs, Carsten, Silakov, Alexey
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5840864/
https://ncbi.nlm.nih.gov/pubmed/28960972
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.7b02113
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