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Evidence for a Di-μ-oxo Diamond Core in the Mn(IV)/Fe(IV) Activation Intermediate of Ribonucleotide Reductase from Chlamydia trachomatis

High-valent iron and manganese complexes effect some of the most challenging biochemical reactions known, including hydrocarbon and water oxidations associated with the global carbon cycle and oxygenic photosynthesis, respectively. Their extreme reactivity presents an impediment to structural charac...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Martinie, Ryan J., Blaesi, Elizabeth J., Krebs, Carsten, Bollinger, J. Martin, Silakov, Alexey, Pollock, Christopher J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5518598/
https://ncbi.nlm.nih.gov/pubmed/28075562
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11563
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