Visualizing the reaction cycle in an iron(II)- and 2-(oxo)-glutarate-dependent hydroxylase

Iron(II)- and 2-(oxo)-glutarate-dependent oxygenases catalyze diverse oxidative transformations that are often initiated by abstraction of hydrogen from carbon by iron(IV)-oxo (ferryl) complexes. Control of the relative orientation of the substrate C–H and ferryl Fe–O bonds, primarily by direction o...

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Publicado en:J Am Chem Soc
Autores principales: Mitchell, Andrew J., Dunham, Noah P., Martinie, Ryan J., Bergman, Jonathan A., Pollock, Christopher J., Hu, Kai, Allen, Benjamin D., Chang, Wei-chen, Silakov, Alexey, Bollinger, J. Martin, Krebs, Carsten, Boal, Amie K.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2017
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5852378/
https://ncbi.nlm.nih.gov/pubmed/28823155
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b07374
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