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Cryoreduction of the NO-Adduct of Taurine:α-Ketoglutarate Dioxygenase (TauD) Yields an Elusive {FeNO}(8) Species
The Fe(II)- and α-ketoglutarate (αKG)-dependent enzymes are a functionally and mechanistically diverse group of mononuclear nonheme-iron enzymes that activate dioxygen to couple the decarboxylation of αKG, which yields succinate and CO(2), to the oxidation of an aliphatic C–H bond of their substrate...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3931003/ https://ncbi.nlm.nih.gov/pubmed/20218714 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja909715g |
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