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Electronic Structure Analysis of the Oxygen-Activation Mechanism by Fe(II)- and α-Ketoglutarate (αKG)-Dependent Dioxygenases
α-Ketoglutarate (αKG)-dependent nonheme iron enzymes utilize a high-spin (HS) ferrous center to couple the activation of oxygen to the decarboxylation of the cosubstrate αKG to yield succinate and CO(2), and to generate a high-valent ferryl species that then acts as an oxidant to functionalize the t...
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| Main Authors: | , , , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2012
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3955955/ https://ncbi.nlm.nih.gov/pubmed/22511515 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201102829 |
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