Metallaphotoredox-Catalyzed Cross-Electrophile C(sp)(3)─C(sp)(3) Coupling of Aliphatic Bromides

A strategy for the installation of small alkyl fragments onto pharmaceutically relevant aliphatic structures has been established via metallaphotoredox catalysis. Herein, we report that tris(trimethylsilyl)silanol can be employed as an effective halogen abstraction reagent that, in combination with...

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Détails bibliographiques
Publié dans:J Am Chem Soc
Auteurs principaux: Smith, Russell T., Zhang, Xiaheng, Rincón, Juan A., Agejas, Javier, Mateos, Carlos, Barberis, Mario, García-Cerrada, Susana, de Frutos, Oscar, MacMillan, David W. C.
Format: Artigo
Langue:Inglês
Publié: 2018
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Article
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6697083/
https://ncbi.nlm.nih.gov/pubmed/30516995
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b12025
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