Metallaphotoredox-Catalyzed Cross-Electrophile C(sp)(3)─C(sp)(3) Coupling of Aliphatic Bromides

A strategy for the installation of small alkyl fragments onto pharmaceutically relevant aliphatic structures has been established via metallaphotoredox catalysis. Herein, we report that tris(trimethylsilyl)silanol can be employed as an effective halogen abstraction reagent that, in combination with...

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Publicado en:J Am Chem Soc
Main Authors: Smith, Russell T., Zhang, Xiaheng, Rincón, Juan A., Agejas, Javier, Mateos, Carlos, Barberis, Mario, García-Cerrada, Susana, de Frutos, Oscar, MacMillan, David W. C.
Formato: Artigo
Idioma:Inglês
Publicado: 2018
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6697083/
https://ncbi.nlm.nih.gov/pubmed/30516995
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b12025
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