Metallaphotoredox-Catalyzed Cross-Electrophile C(sp)(3)─C(sp)(3) Coupling of Aliphatic Bromides

A strategy for the installation of small alkyl fragments onto pharmaceutically relevant aliphatic structures has been established via metallaphotoredox catalysis. Herein, we report that tris(trimethylsilyl)silanol can be employed as an effective halogen abstraction reagent that, in combination with...

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Bibliografiska uppgifter
I publikationen:J Am Chem Soc
Huvudupphovsmän: Smith, Russell T., Zhang, Xiaheng, Rincón, Juan A., Agejas, Javier, Mateos, Carlos, Barberis, Mario, García-Cerrada, Susana, de Frutos, Oscar, MacMillan, David W. C.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2018
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Article
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC6697083/
https://ncbi.nlm.nih.gov/pubmed/30516995
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b12025
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