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Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp(3)-sp(2) Cross-Coupling of Oxalates with Aryl Halides

Alkyl oxalates, prepared from their corresponding alcohols, are engaged for the first time as carbon radical fragments in metallaphotoredox catalysis. In this report, we demonstrate that alcohols, native organic functional groups, can be readily activated with simple oxalyl chloride to become radica...

詳細記述

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書誌詳細
出版年:J Am Chem Soc
主要な著者: Zhang, Xiaheng, MacMillan, David W. C.
フォーマット: Artigo
言語:Inglês
出版事項: 2016
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC5464990/
https://ncbi.nlm.nih.gov/pubmed/27718570
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b09533
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