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Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp(3)-sp(2) Cross-Coupling of Oxalates with Aryl Halides

Alkyl oxalates, prepared from their corresponding alcohols, are engaged for the first time as carbon radical fragments in metallaphotoredox catalysis. In this report, we demonstrate that alcohols, native organic functional groups, can be readily activated with simple oxalyl chloride to become radica...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Zhang, Xiaheng, MacMillan, David W. C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5464990/
https://ncbi.nlm.nih.gov/pubmed/27718570
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b09533
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