Lataa...
Direct Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O(2) and NO and Mechanistic Insights into Metal Mediated Peroxynitrite Decomposition
We report the formation of a new copper peroxynitrite (PN) complex [Cu(II)(TMG(3)tren)(κ(1)-OONO)](+) (PN1) from reaction of [Cu(II)(TMG(3)tren)(O(2)(•–))](+) (1) with NO(•)((g)) at –125 ºC. The first resonance Raman spectroscopic characterization of such a metal bound PN moiety supports a cis κ(1)-...
Tallennettuna:
| Julkaisussa: | Angew Chem Int Ed Engl |
|---|---|
| Päätekijät: | , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2019
|
| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6685550/ https://ncbi.nlm.nih.gov/pubmed/31158311 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201904672 |
| Tagit: |
Lisää tagi
Ei tageja, Lisää ensimmäinen tagi!
|