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Direct Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O(2) and NO and Mechanistic Insights into Metal Mediated Peroxynitrite Decomposition
We report the formation of a new copper peroxynitrite (PN) complex [Cu(II)(TMG(3)tren)(κ(1)-OONO)](+) (PN1) from reaction of [Cu(II)(TMG(3)tren)(O(2)(•–))](+) (1) with NO(•)((g)) at –125 ºC. The first resonance Raman spectroscopic characterization of such a metal bound PN moiety supports a cis κ(1)-...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6685550/ https://ncbi.nlm.nih.gov/pubmed/31158311 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201904672 |
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