Direct Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O(2) and NO and Mechanistic Insights into Metal Mediated Peroxynitrite Decomposition

We report the formation of a new copper peroxynitrite (PN) complex [Cu(II)(TMG(3)tren)(κ(1)-OONO)](+) (PN1) from reaction of [Cu(II)(TMG(3)tren)(O(2)(•–))](+) (1) with NO(•)((g)) at –125 ºC. The first resonance Raman spectroscopic characterization of such a metal bound PN moiety supports a cis κ(1)-...

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Detaylı Bibliyografya
Yayımlandı:Angew Chem Int Ed Engl
Asıl Yazarlar: Liu, Jeffrey J., Siegler, Maxime A., Karlin, Kenneth D., Moënne-Loccoz, Pierre
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2019
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Article
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC6685550/
https://ncbi.nlm.nih.gov/pubmed/31158311
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201904672
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