Reactions of Co(III)–Nitrosyl Complexes with Superoxide and Their Mechanistic Insights

New Co(III)-nitrosyl complexes bearing N-tetramethylated cyclam (TMC) ligands, [(12-TMC)Co(III)(NO)](2+) (1) and [(13-TMC)Co(III)(NO)](2+) (2), were synthesized via [(TMC)Co(II)(CH(3)CN)](2+) plus NO((g)) reactions. Spectroscopic and structural characterization shows that these compounds bind the ni...

Celý popis

Uloženo v:
Podrobná bibliografie
Vydáno v:J Am Chem Soc
Hlavní autoři: Kumar, Pankaj, Lee, Yong-Min, Park, Young Jun, Siegler, Maxime A., Karlin, Kenneth D., Nam, Wonwoo
Médium: Artigo
Jazyk:Inglês
Vydáno: 2015
Témata:
Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4523085/
https://ncbi.nlm.nih.gov/pubmed/25793706
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja513234b
Tagy: Přidat tag
Žádné tagy, Buďte první, kdo otaguje tento záznam!

Podobné jednotky