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Reactions of Co(III)–Nitrosyl Complexes with Superoxide and Their Mechanistic Insights
New Co(III)-nitrosyl complexes bearing N-tetramethylated cyclam (TMC) ligands, [(12-TMC)Co(III)(NO)](2+) (1) and [(13-TMC)Co(III)(NO)](2+) (2), were synthesized via [(TMC)Co(II)(CH(3)CN)](2+) plus NO((g)) reactions. Spectroscopic and structural characterization shows that these compounds bind the ni...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4523085/ https://ncbi.nlm.nih.gov/pubmed/25793706 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja513234b |
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