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Exclusive Imidazole Ligation to Cu(III)(2)O(2) and Cu(III)Cu(II)(2)O(2) Cores

We disclose herein the synthesis and characterization of L(2)Cu(III)(2)O(2) and L(3)Cu(III)Cu(II)(2)O(2) complexes with nitrogen ligation exclusively from imidazoles for the first time. Their accessibility by direct oxygenation of a L-Cu(I) precursor and the resulting Cu(III) formation inform on the...

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Publicado en:Chem Commun (Camb)
Main Authors: Keown, William, Large, Tao A. G., Chiang, Linus, Wasinger, Erik C., Stack, T. Daniel P.
Formato: Artigo
Idioma:Inglês
Publicado: 2019
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6658085/
https://ncbi.nlm.nih.gov/pubmed/31173011
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9cc02982f
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