Synthesis and characterization of a high-valent heterobimetallic [Cu(III)(μ-O)(2)Ni(III)](2+) core involving nucleophilic oxo groups()

A heterobimetallic CuNi bis(μ-oxo) diamond core is shown to possess nucleophilic oxo groups, and has been demonstrated for the first time as a viable intermediate during the deformylation of fatty aldehydes by cyanobacterial aldehyde decarbonylase.

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Detalhes bibliográficos
Main Authors: Kundu, Subrata, Pfaff, Florian Felix, Miceli, Enrico, Zaharieva, Ivelina, Herwig, Christian, Yao, Shenglai, Farquhar, Erik R., Kuhlmann, Uwe, Bill, Eckhard, Hildebrandt, Peter, Dau, Holger, Driess, Matthias, Limberg, Christian, Ray, Kallol
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4084805/
https://ncbi.nlm.nih.gov/pubmed/23589478
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201300861
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