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C–H activation and nucleophilic substitution in a photochemically generated high valent iron complex
The photochemical oxidation of a (TAML)Fe(III) complex 1 using visible light generated Ru(bpy)(3)(3+) produces valence tautomers (TAML)Fe(IV) (1(+)) and (TAML˙(+))Fe(III) (1-TAML˙(+)), depending on the exogenous anions. The presence of labile Cl(–) or Br(–) results in a ligand-based oxidation and st...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5944818/ https://ncbi.nlm.nih.gov/pubmed/29862004 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05378a |
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