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Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups
Oxidation of phenols by heterodinuclear Cu(III)(μ-O)(2)Ni(III) complexes containing nucleophilic oxo groups occurs by both proton coupled electron transfer (PCET) and hydrogen atom transfer (HAT) mechanisms; the exact mechanism depends on the nature of the phenol as well as the substitution pattern...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4201338/ https://ncbi.nlm.nih.gov/pubmed/24362244 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3dt52644e |
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