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Phenolate Hydroxylation in a Bis(μ-oxo)dicopper(III) Complex: Lessons from the Guanidine/Amine Series
A new hybrid permethylated-amine-guanidine ligand based on a 1,3-propanediamine backbone ((2)L) and its Cu–O(2) chemistry is reported. [((2)L)Cu(I)(MeCN)](1+) complex readily oxygenates at low temperatures in polar aprotic solvents to form a bis(μ-oxo)dicopper(III) (O) species (2b), similar to the p...
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| Principais autores: | , , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2663633/ https://ncbi.nlm.nih.gov/pubmed/19119846 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja807809x |
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