Phenolate Hydroxylation in a Bis(μ-oxo)dicopper(III) Complex: Lessons from the Guanidine/Amine Series

A new hybrid permethylated-amine-guanidine ligand based on a 1,3-propanediamine backbone ((2)L) and its Cu–O(2) chemistry is reported. [((2)L)Cu(I)(MeCN)](1+) complex readily oxygenates at low temperatures in polar aprotic solvents to form a bis(μ-oxo)dicopper(III) (O) species (2b), similar to the p...

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Hauptverfasser: Herres-Pawlis, Sonja, Verma, Pratik, Haase, Roxana, Kang, Peng, Lyons, Christopher T., Wasinger, Erik C., Flörke, Ulrich, Henkel, Gerald, Stack, T. Daniel P.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2009
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2663633/
https://ncbi.nlm.nih.gov/pubmed/19119846
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja807809x
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