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Selective Oxidation of Exogenous Substrates by a Bis-Cu(III) Bis-Oxide Complex: Mechanism and Scope

Cu(III)(2)(μ-O)(2) bis-oxides (O) form spontaneously by direct oxygenation of nitrogen-chelated Cu(I) species and constitute a diverse class of versatile 2e(-)/2H(+) oxidants, but while these species have attracted attention as biomimetic models for dinuclear Cu enzymes, reactivity is typically limi...

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Bibliografske podrobnosti
izdano v:Inorganica Chim Acta
Main Authors: Large, Tao A. G., Mahadevan, Viswanath, Keown, William, Stack, T. Daniel P.
Format: Artigo
Jezik:Inglês
Izdano: 2018
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6724545/
https://ncbi.nlm.nih.gov/pubmed/31485082
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ica.2018.11.027
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