The Bis(μ–oxo) Dicopper(III) Species of the Simplest Peralkylated Diamine: Enhanced Reactivity towards Exogenous Substrates

N,N,N′,N′-tetramethylethylenediamine (TMED), the simplest and most extensively used peralkylated diamine ligand, is conspicuously absent from those known to form a bis(μ–oxo)dicopper(III) (O) species, [(TMED)(2)Cu(III)(2)O(2)](2+), upon oxygenation of its Cu(I) complex. Presented here is the charact...

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Autores principales: Kang, Peng, Bobyr, Elena, Dustman, John, Hodgson, Keith O., Hedman, Britt, Solomon, Edward I., Stack, T. Daniel P.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2010
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2993838/
https://ncbi.nlm.nih.gov/pubmed/21028910
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic101515g
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