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Simplest Monodentate Imidazole Stabilization of the oxy-Tyrosinase Cu(2)O(2) Core: Phenolate Hydroxylation through a Cu(III) Intermediate
Tyrosinases (Ty) are ubiquitous binuclear copper enzymes that oxygenate to Cu(II)(2)O(2) ((S)P) cores bonded by three histidine Nτ-imidazoles per Cu center. Synthetic monodentate imidazole bonded (S)P species self-assemble in a near quantitative manner at −125°C, but Nπ-ligation has been required. H...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5470875/ https://ncbi.nlm.nih.gov/pubmed/27440390 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201605159 |
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