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Catalytic, Enantioselective Synthesis of Cyclic Carbamates from Dialkyl Amines by CO(2)-Capture: Discovery, Development, and Mechanism
Cyclic carbamates are a common feature of small molecule therapeutics, offering a constrained hydrogen bond acceptor that is both polar and sterically small. Methods for their preparation most often focus first on aminoalcohol synthesis and then reaction with phosgene or its equivalent. This report...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6528176/ https://ncbi.nlm.nih.gov/pubmed/30582326 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b11793 |
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