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Diastereoselective Silylene Transfer Reactions to Chiral Enantiopure Alkenes: Effects of Ligand Size and Substrate Bias

Silylenes are useful reactive intermediates for the stereoselective construction of compounds containing carbon–silicon bonds. Despite their synthetic utility, the development of either an enantioselective or diastereoselective metal-catalyzed silylene transfer reaction in which ligands on the metal...

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Detalhes bibliográficos
Publicado no:Dalton Trans
Main Authors: Rotsides, Christina Z., Woerpel, K. A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6498443/
https://ncbi.nlm.nih.gov/pubmed/28224150
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6dt04612f
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