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Asymmetric Chiral Ligand-Directed Alkene Dioxygenation
[Image: see text] A Pd-catalyzed asymmetric alkene 1,2-dioxygenation reaction is described. The diastereoselectivity of the reaction is controlled by tethering a chiral oxime ether directing group to the alkene substrate. The best selectivities are obtained with 8-substituted menthone-derived oxime...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3600423/ https://ncbi.nlm.nih.gov/pubmed/23249401 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol303003g |
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