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Diastereoselective Coupling of Chiral Acetonide Trisubstituted Radicals with Alkenes
The stereochemical outcome of reactions of chiral nucleophilic trisubstituted acetonide radicals with electron-deficient alkenes is dictated by a delicate balance between destabilizing non-bonding interactions and stabilizing hydrogen-bonding between substituents on the α and β carbons.
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Publicado no: | Chemistry |
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Main Authors: | , , , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2016
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4978530/ https://ncbi.nlm.nih.gov/pubmed/27128888 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201601957 |
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