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Diastereoselective Coupling of Chiral Acetonide Trisubstituted Radicals with Alkenes
The stereochemical outcome of reactions of chiral nucleophilic trisubstituted acetonide radicals with electron-deficient alkenes is dictated by a delicate balance between destabilizing non-bonding interactions and stabilizing hydrogen-bonding between substituents on the α and β carbons.
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| Publicat a: | Chemistry |
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| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2016
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4978530/ https://ncbi.nlm.nih.gov/pubmed/27128888 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201601957 |
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