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Diastereoselective Synthesis of Seven-Membered Ring trans-Alkenes from Dienes and Aldehydes by Silylene Transfer

Silver-catalyzed silylene transfer to alkenes formed vinylsilacyclopropanes regioselectively. These allylic silanes underwent additions to aldehydes to form seven-membered ring trans-alkenes with high diastereoselectivity. The high reactivity of the trans alkenes is evidenced by their formal [1,3]-s...

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Bibliographische Detailangaben
Hauptverfasser: Greene, Margaret A., Prévost, Michel, Tolopilo, Joshua, Woerpel, K. A.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2012
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3437758/
https://ncbi.nlm.nih.gov/pubmed/22780578
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja305713v
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