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Silylene-Mediated Ring Contraction of Homoallylic Ethers to Form Allylic Silanes
[Image: see text] (—)-Isopulegol derivatives undergo a ring contraction under silylene-mediated conditions to provide cyclopentane products. Silylene transfer to other homoallylic ethers did not provide the ring contraction products. Allylic silane products were elaborated to determine the stereoche...
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| Auteurs principaux: | , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2009
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2749648/ https://ncbi.nlm.nih.gov/pubmed/19681592 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo901111j |
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