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Silylene-Mediated Ring Contraction of Homoallylic Ethers to Form Allylic Silanes

[Image: see text] (—)-Isopulegol derivatives undergo a ring contraction under silylene-mediated conditions to provide cyclopentane products. Silylene transfer to other homoallylic ethers did not provide the ring contraction products. Allylic silane products were elaborated to determine the stereoche...

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Detalhes bibliográficos
Main Authors: Bourque, Laura E., Haile, Pamela A., Woerpel, K. A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2749648/
https://ncbi.nlm.nih.gov/pubmed/19681592
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo901111j
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