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Chiral Bifunctional Phosphine Ligand Enabling Gold-Catalyzed Asymmetric Isomerization of Alkyne to Allene and Asymmetric Synthesis of 2,5-Dihydrofuran
The asymmetric isomerization of alkyne to allene is the most efficient and the completely atom-economic approach to this class of versatile axial chiral structure. However, the state-of-the-art is limited to tert- butyl alk-3-ynoate substrates that possess requisite acidic propargylic C–H bonds. Rep...
Shranjeno v:
| izdano v: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2019
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6492927/ https://ncbi.nlm.nih.gov/pubmed/30789268 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b12833 |
| Oznake: |
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