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Bifunctional Ligand Enables Efficient Gold-Catalyzed Hydroalkenylation of Propargylic Alcohol
Using our previously designed biphenyl-2-ylphosphine L2 featuring a remote tertiary amino group as an enabling ligand, we have developed the first gold-catalyzed intermolecular hydroalkenylation of alkynes. Synthetically valuable conjugated dienyl alcohols are formed in moderate to good yields. A ra...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6592274/ https://ncbi.nlm.nih.gov/pubmed/29704310 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201802533 |
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