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Regioselective Dihalohydration Reactions of Propargylic Alcohols: Gold-Catalyzed and Noncatalyzed Reactions**

The regioselective conversion of propargylic alcohols into previously unreported α,α-diiodo-β-hydroxyketones was achieved by treatment with N-iodosuccinimide in the presence of a gold catalyst. The corresponding α,α-dichloro-β-hydroxyketones were obtained by treatment with trichloroisocyanuric acid...

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Vydáno v:Angew Chem Int Ed Engl
Hlavní autoři: D’Oyley, Jarryl M, Aliev, Abil E, Sheppard, Tom D
Médium: Artigo
Jazyk:Inglês
Vydáno: WILEY-VCH Verlag 2014
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4271674/
https://ncbi.nlm.nih.gov/pubmed/25147077
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201405348
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