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Photoredox‐Catalyzed Cyclobutane Synthesis by a Deboronative Radical Addition–Polar Cyclization Cascade

Photoredox‐catalyzed methylcyclobutanations of alkylboronic esters are described. The reactions proceed through single‐electron transfer induced deboronative radical addition to an electron‐deficient alkene followed by single‐electron reduction and polar 4‐exo‐tet cyclization with a pendant alkyl ha...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Shu, Chao, Noble, Adam, Aggarwal, Varinder K.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6492184/
https://ncbi.nlm.nih.gov/pubmed/30681266
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201813917
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