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Arynes as Radical Acceptors: TEMPO‐Mediated Cascades Comprising Addition, Cyclization, and Trapping
The application of arynes as radical acceptors is described. The stable radical TEMPO (2,2,6,6‐tetramethyl piperidine 1‐oxyl) is shown to add to various ortho‐substituted benzynes generating the corresponding aryl radicals which engage in 5‐exo or 6‐endo cyclizations. The cyclized radicals are event...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7839731/ https://ncbi.nlm.nih.gov/pubmed/33038065 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202012654 |
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