Synthesis of Functionalized Cyclopropanes from Carboxylic Acids by a Radical Addition–Polar Cyclization Cascade

Herein, we describe the development of a photoredox‐catalyzed decarboxylative radical addition–polar cyclization cascade approach to functionalized cyclopropanes. Reductive termination of radical–polar crossover reactions between aliphatic carboxylic acids and electron‐deficient alkenes yielded carb...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Shu, Chao, Mega, Riccardo S., Andreassen, Björn J., Noble, Adam, Aggarwal, Varinder K.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2018
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6282618/
https://ncbi.nlm.nih.gov/pubmed/30204292
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201808598
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