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Visible‐Light‐Mediated Decarboxylative Radical Additions to Vinyl Boronic Esters: Rapid Access to γ‐Amino Boronic Esters

The synthesis of alkyl boronic esters by direct decarboxylative radical addition of carboxylic acids to vinyl boronic esters is described. The reaction proceeds under mild photoredox catalysis and involves an unprecedented single‐electron reduction of an α‐boryl radical intermediate to the correspon...

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Bibliografski detalji
Izdano u:Angew Chem Int Ed Engl
Glavni autori: Noble, Adam, Mega, Riccardo S., Pflästerer, Daniel, Myers, Eddie L., Aggarwal, Varinder K.
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2018
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5838549/
https://ncbi.nlm.nih.gov/pubmed/29316095
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201712186
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