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Visible‐Light‐Mediated Decarboxylative Radical Additions to Vinyl Boronic Esters: Rapid Access to γ‐Amino Boronic Esters

The synthesis of alkyl boronic esters by direct decarboxylative radical addition of carboxylic acids to vinyl boronic esters is described. The reaction proceeds under mild photoredox catalysis and involves an unprecedented single‐electron reduction of an α‐boryl radical intermediate to the correspon...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Noble, Adam, Mega, Riccardo S., Pflästerer, Daniel, Myers, Eddie L., Aggarwal, Varinder K.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5838549/
https://ncbi.nlm.nih.gov/pubmed/29316095
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201712186
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