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Spin Interconversion of Heme-Peroxo-Copper Complexes Facilitated by Intramolecular Hydrogen-Bonding Interactions
Synthetic peroxo-bridged high-spin (HS) heme-(μ-η(2):η(1)-O(2)(2−))-Cu(L) complexes incorporating (as part of the copper ligand) intramolecular hydrogen-bond (H-bond) capabilities and/or steric effects are herein demonstrated to affect the complex’s electronic and geometric structure, notably impact...
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| Udgivet i: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6457345/ https://ncbi.nlm.nih.gov/pubmed/30836005 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b00118 |
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